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ACS_ACCOUNT of chemical research

21 Apr 2019





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April 16, 2019

Volume 52, Issue 4

Pages 849-1144


Metathesis cyclopolymerization of α,ω-diynes is a powerful method to prepare functional polyacetylenes. Recently, 

Grubbs-type catalysts have emerged as excellent catalysts for this polymerization. In addition to their high reactivity, 

good stability, and accessibility, Grubbs-type catalysts enable polyacetylene to be prepared with controlled regiochemistry, 

stereochemistry, molecular weight, and molecular weight dispersity.

http://pubs.acs.org/toc/achre4/52/4


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